Erling Haaland fired Borussia Dortmund past Schalke in the Revierderby while Robert Lewandowski hit the perfect hat-trick to become the first Bundesliga player ever to reach 10 goals from just five games and Dayot Upamecano kept RB Leipzig top of the table.
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Erling Haaland, Manuel Akanji and Mats Hummels did the damage as Dortmund kept pace at the top of the table with a comfortable 3-0 triumph over local rivals Schalke.
Robert Lewandowski scored a hat-trick, Leroy Sane a comeback strike and Jamal Musiala second Bundesliga goal as Bayern thrashed Frankfurt at the Allianz Arena.
Dayot Upamecano scored for the first time since 2018 as Leipzig came from a goal down against 10-man Hertha to win and stay top of the table, with Marcel Sabitzer scoring the winning goal on his return from injury.
Jean-Philippe Mateta's brace was not enough for struggling Mainz, as goals from Lars Stindl, Jonas Hofmann and Matthias Ginter earned Gladbach the points in a 3-2 win.
Wolfsburg withstood a late Bielefeld fightback as earlier goals from Wout Weghorst and Maximilian Arnold fired the 2008/09 Bundesliga champions to their first win of the season.
Maximillian Eggestein scored inside five minutes for Bremen, but Dennis Geiger's goal earned Hoffenheim a point away from home on Sunday which could have been three if not for missed chances.
Orel Mangala scored the 2020/21 season's fastest goal after just 24 seconds but Cologne clawed their way back into the game and Sebastian Andersson's penalty earned them a point with a 1-1 draw in Stuttgart on Friday.
Vincenzo Grifo scored a superb goal as Freiburg battled to a hard-earned point away to Union on Matchday 5 on Saturday.
Lucas Alario continued his scoring streak with a brace as Leverkusen moved into the top four with victory at home to Augsburg.